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Synthesis, characterization, electrospinning and antibacterial studies on triphenylphosphine-dithiphosphonates Copper(I) and Silver(I) complexes

Overview of attention for article published in BMC Chemistry, March 2014
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Title
Synthesis, characterization, electrospinning and antibacterial studies on triphenylphosphine-dithiphosphonates Copper(I) and Silver(I) complexes
Published in
BMC Chemistry, March 2014
DOI 10.1186/1752-153x-8-18
Pubmed ID
Authors

Mehmet Karakus, Yuksel Ikiz, Halil Ibrahim Kaya, Omer Simsek

Abstract

The novel amido and O-ferrocenyldithiophosphonates [FcP(S)(SH)(NHR1)] (Fc = Fe(η5-C5H5)(η5-C5H4), R1 = 1-(4-fluorophenylethyl and benzyloxycyclopentyl) and [FcP(S)(OR2)S-][H3N+C(CH3)3] (R2 = myrtanyl) were synthesized by the reaction of [(FcPS2)]2 (Fc = Fe(η5-C5H5)(η5-C5H4)) and chiral amines, such as (S)-(-)-1-(4-fluorophenylethyl) amine and (1S,2S)-(+)-benzyloxycyclopentyl amine, and of (1S), (2S), (5S)-myrtanol in toluene. The reaction of ferrocenyldithiophosphonates and [Cu(PPh3)2]NO3 or AgNO3 and PPh3 gave rise to copper(I) and silver(I) complexes in THF. [Ag2{FcP(OMe)S2}2(PPh3)2] and [Cu(PPh3)2]NO3 were embedded into nanofibers and their antimicrobial activities on fibers were also investigated.

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The data shown below were compiled from readership statistics for 24 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
United Kingdom 1 4%
Unknown 23 96%

Demographic breakdown

Readers by professional status Count As %
Researcher 8 33%
Student > Master 5 21%
Unspecified 2 8%
Student > Ph. D. Student 2 8%
Student > Doctoral Student 1 4%
Other 2 8%
Unknown 4 17%
Readers by discipline Count As %
Chemistry 10 42%
Agricultural and Biological Sciences 2 8%
Unspecified 2 8%
Materials Science 2 8%
Engineering 2 8%
Other 0 0%
Unknown 6 25%