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Electron ionization mass spectral fragmentation study of sulfation derivatives of polychlorinated biphenyls

Overview of attention for article published in BMC Chemistry, March 2009
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Title
Electron ionization mass spectral fragmentation study of sulfation derivatives of polychlorinated biphenyls
Published in
BMC Chemistry, March 2009
DOI 10.1186/1752-153x-3-5
Pubmed ID
Authors

Xueshu Li, Larry W Robertson, Hans-Joachim Lehmler

Abstract

Polychlorinated biphenyls are persistent organic pollutants that can be metabolized via hydroxylated PCBs to PCB sulfate metabolites. The sensitive and selective analysis of PCB sulfate monoesters by gas chromatography-mass spectrometry (GC-MS) requires their derivatization, for example, as PCB 2,2,2-trichloroethyl (TCE) sulfate monoesters. To aid in the identification of unknown PCB sulfate metabolites isolated from biological samples, the electron impact MS fragmentation pathways of selected PCB TCE sulfate diesters were analyzed and compared to the fragmentation pathways of the corresponding methoxylated PCBs.

Mendeley readers

Mendeley readers

The data shown below were compiled from readership statistics for 9 Mendeley readers of this research output. Click here to see the associated Mendeley record.

Geographical breakdown

Country Count As %
Japan 1 11%
United States 1 11%
Unknown 7 78%

Demographic breakdown

Readers by professional status Count As %
Student > Bachelor 2 22%
Student > Master 2 22%
Student > Ph. D. Student 2 22%
Lecturer > Senior Lecturer 1 11%
Researcher 1 11%
Other 1 11%
Readers by discipline Count As %
Environmental Science 2 22%
Pharmacology, Toxicology and Pharmaceutical Science 2 22%
Chemistry 2 22%
Biochemistry, Genetics and Molecular Biology 1 11%
Engineering 1 11%
Other 0 0%
Unknown 1 11%